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Hazardous Chemical Alternatives

Topic:

The table below lists some possible alternatives to chemicals routinely used in the laboratory. The alternatives represent less toxic or non-hazardous materials that will help in reducing hazardous waste generation.

ORIGINAL MATERIAL

SUBSTITUTE

COMMENTS

Acetamide

Stearic Acid

In phase change and freezing point depression

Benzene

Alcohol

 

Benzoyl peroxide

Lauryl peroxide

When used as a polymer catalyst

Carbon tetrachloride

Cyclohexane

In test for halide ions

Chromic Acid Cleaning Solutions

Alconox, Micro, Pierce RBS-35, or similar detergents

In glassware cleaning

Formaldehyde

Peracetic Acid

In cleaning of kidney dialysis machines

Formaldehyde

“Formalternate” (Flinn Scientific) or Ethanol

For storage of biological specimens

Formalin

See Formaldehyde

 

Halogenated Solvents

Non-halogenated solvents

In parts washers or other solvent processes

Mercuric chloride reagent

Amitrole (Kepro Circuit Systems)

Circuit board etching

Mercury salts

Mercury free catalysts (e.g. CuSO4TiO2K2SO4)

Kjeldahl digests

Mercury Thermometers

Mineral spirit filled, stainless steel, bimetal, digital

 

Mercuric chloride (biocide)

5-10% Methylene chloride, 1% formalin, 1 N hydrochloric acid, Sodium azide, Sodium hypochlorite

 

Sodium Dichromate

Sodium hypochlorite

 

Sulfide ion

Hydroxide ion

In analysis of heavy metals

Wood’s metal

Onion’s fusible alloy

 

Xylene or Toluene

Simple alcohols and ketones

 

Xylene or Toluene scintillation cocktails

Non-hazardous proprietary liquid scintillation cocktails

In radioactive tracer studies